Product ID:UNLEADED GASOLINE
MSDS Date:01/29/1991
FSC:9130
NIIN:00-148-7103
MSDS Number: BVGZK

TOTAL PETROLEUM INC

EAST SUPERIOR STREET
ALMA, MI 48802
US

Emergency Phone: 800-424-9300(CHEMTREC)/517-463-1164

Info Phone: 517-463-1164

Preparer: M.N. MARTIN

Cage: 6G102

TOTAL PETROLEUM INC

ALMA, MI 48801 US

Telephone: 517-463-1164

Cage: 6G102

GASOLINE (89 FORMULA OCTANE)

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM/500STEL;9394

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <2.5%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2; 9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <1.6%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE (P-DIMETHYLBENZENE) (SARA III)

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: <1.5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-XYLENE (M-DIMETHYLBENZENE) (SARA III)

CAS: 108-38-3

RTECS: ZE2275000

Fraction By Weight: <4.0%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/15OSTEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

O-XYLENE (O-DIMETHYLBENZENE) (SARA III)

CAS: 95-47-6

RTECS: ZE2450000

Fraction By Weight: <1.5%

OSHA PEL 100PPM

ACGIH TLV: 100 PPM/150STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <2.5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9394

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <7.0%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PENTANE

CAS: 109-66-0

RTECS: RZ9450000

Fraction By Weight: <3%

OSHA PEL 1000 PPM

ACGIH TLV: 600 PPM/750STEL;9394

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <3.0%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

HEXANE (OTHER ISOMERS)

Fraction By Weight: <10%

OSHA PEL 500 PPM (PER MSDS)

ACGIH TLV: 500 PPM (PER MSDS)

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:CENTRAL NERVOUS SYSTEM
DEPRESSION, PERIPHERAL NERVOUS SYSTEM DEPRESSION, NARCOSIS,
ASPHYXIATION, GASTROINTESTINAL DISTURBANCES, AND EYE AND SKIN
IRRITATION. CHRONIC:DERMATITIS, PNEUMONITIS, PULM ONARY EDEMA, AND
KIDNEY DAMAGE.
Explanation of Carcinogenicity:NATP/IARC/OSHA HAVE DETERMINED THAT
BENZINE CAUSES LEUKEMIA IN HUMANS.IARC HAS DETERMINED GASOLINE IS
POSSIBLY CARCINOGE
Effects of Overexposure:HEADACHE, DROWSINESS, EYE, RESPIRATORY OR SKIN
IRRIT, NAUSEA, NUMBNESS.
Medical Cond Aggravated by Exposure:NOT APPLICABLE.

First Aid:REMOVE FROM CONTAMINATED ATMOSPHERE. IF NOT BREATHING,
ADMINISTER ARTIFICIAL RESPIRATION. REMOVE CONTAMINATED CLOTHING.
FLUSH AFFECTED AREAS THOROUGHLY WITH WATER. IF SWALLOWED DO NOT
INDUCE VOMITING. SEEK MEDICAL ATTN IMMED.

Flash Point Method:PMCC
Flash Point:<-40F,<-40C
Lower Limits:1.3
Upper Limits:6.0
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS MAY BE
REQUIRED.
Unusual Fire/Explosion Hazard:EXPLOSION HAZ WHEN EXPOSED TO
HEAT/FLAME.VAP HEAVIER THAN AIR & MAY TRAVEL CONSIDERABLE DISTANCE
TO SOURCE OF IGNITION & FLASHBACK.

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. CONTAINE
WITH EARTHEN DIKE OR PETROLEUM ABSORBENT MATERIAL. REMOVE WITH
GROUNDED SUCTION PUMP TO SALVAGE CONTAINER. REMOVE ALL CONTAMINATED
MATERIALS.
Neutralizing Agent:NONE SPECIFIED BY MFG.

Handling and Storage Precautions:KEEP AWAY FROM ALL IGNITION SOURECES
(E.G. HEAT/FLAME/SPARKS/STRONG OXIDIZERS). BOND AND GROUND
CONTAINER. STORE IN SAFETY CONTAINERS.
Other Precautions:NOT APPLICABLE.

Respiratory Protection:ORGANIC VAPOR CARTRIDGE OR SUPPLIED AIR
RESPIRATOR APPROVED BY NIOSH.
Ventilation:LOCAL EXHAUST:TO CONTROL VAPORS. SPECIAL:USE EXPLOSION
PROOF EQUIPMENT. MECHANICAL:FOR CONFINED SPACES.
Protective Gloves:PVC OR EQUIVALENT RESISTANT GLOVES.
Eye Protection:CHEMICAL GOGGLES OR FACE SHIELD.
Other Protective Equipment:PVC OR EQUIVALENT CLOTHING IF SPLASHING IS
LIKELY.
Work Hygienic Practices:KEEP BODY CONTACT AND SPLASH TO A MINIMUM.
Supplemental Safety and Health

HCC:F2
Boiling Pt:B.P. Text:<100F,<38C
Vapor Pres:400-900
Vapor Density:3-4
Spec Gravity:0.65-0.75
Evaporation Rate & Reference:<1, ETHER=1.
Solubility in Water:INSOLUBLE.
Appearance and Odor:SILVER, GREY OR CLEAR LIQUID WITH CHARACTERISTIC
GASOLINE ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZERS.
Stability Condition to Avoid:HEAT AND FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER PETROLEUM
DECOMPOSITION PRODUCTS.

Waste Disposal Methods:PER LOCAL, STATE AND FEDERAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.